产品编号：D428045

产品规格：5mg

产品价格：面议

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产品详情

标准品编号:	D428045
名称:	(11bR)-(–)-4,4-Dibutyl-4,5-dihydro-2,6-bis(3,4,5-trifluorophenyl)-3H-dinaphth[2,1-c:1′,2′-e]azepinium Bromide
别名:	4,4-Dibutyl-2,6-bis(3,4,5-trifluorophenyl)-4,5-dihydro-3H-dinaphtho[2,1-c:1',2'-e]azepin-4-ium Bromide; (11bR)-4,4-Dibutyl-4,5-dihydro-2,6-bis(3,4,5-trifluorophenyl)-3H-Dinaphth[2,1-c:1',2'-e]azepinium Bromide (1:1);
CAS号:	887938-70-7
参考CAS号:	Component: 887972-90-9
分子式:	C₄₂H₃₆F₆N•Br
分子量:	668.73799
种类:	Building Blocks; Catalyst;
应用:	(11bR)-(–)-4,4-Dibutyl-4,5-dihydro-2,6-bis(3,4,5-trifluorophenyl)-3H-dinaphth[2,1-c:1′,2′-e]azepinium Bromide is widely used as a catalyst in synthetic preparations. It is used as phase-transfer catalyst in monoalkylation of glycinate Schiff base using alkyl halides. It is also used in stereoselective preparation of amino acids derivatives using enantioselective substitution of imino esters with arene chromium complexes.
参考文献	Ooi, T., et al.: Tetrahedron: Asymmetry, 17, 603 (2006); Shirakawa, S., et al.: Angew. Chem. Int. Ed., 54, 838 (2015);