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产品基本信息
产品编号：E890335
产品名称：(R,R)-(-)-1,2-Ethanediylbis[(2-methoxyphenyl)phenylphosphine]rhodium(I) Tetrafluoroborate
产品CAS：56977-92-5
规格含量：10mg
产品价格：面议
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产品详细介绍
标准品编号:
E890335
名称:
(R,R)-(-)-1,2-Ethanediylbis[(2-methoxyphenyl)phenylphosphine]rhodium(I) Tetrafluoroborate
别名:
(R,R)-(-)-1,2-Bis[(o-methoxyphenyl)(phenyl)phosphino]ethane(1,5-cyclooctadiene)rhodium(I) Tetrafluoroborate; [(1,2,5,6-η)-1,5-Cyclooctadiene][(1R,1'R)-1,2-ethanediylbis[(2-methoxyphenyl)phenylphosphine-κP]]rhodium(1+) Tetrafluoroborate(1-); [R-(R*,R*)]-[(1,2,5,6-η)-1,5-Cyclooctadiene][1,2-ethanediylbis[(2-methoxyphenyl)phenylphosphine]-P,P']rhodium(1+) Tetrafluoroborate(1-); 1,5-Cyclooctadiene Rhodium Complex; 1,2-Ethanediylbis[(2-methoxyphenyl)phenylphosphine Rhodium Complex; [R-(R*,R*)]- [(1,2,5,6-η)-1,5-Cyclooctadiene][1,2-ethanediylbis[(2-methoxyphenyl)phenylphosphine-κP]]rhodium(1+) Tetrafluoroborate(1-)
CAS号:
56977-92-5
分子式:
C₃₆H₄₀BF₄O₂P₂Rh
分子量:
756.36
种类:
Building Blocks; Catalyst;
应用:
(R,R)-(-)-1,2-Ethanediylbis[(2-methoxyphenyl)phenylphosphine]rhodium(I) Tetrafluoroborate is used as a catalyst in the synthesis of Sinefungin (S487100); a natural nucleoside analog of S-adenosylmethionine that inhibits Streptococcus pneumoniae biofilm growth. Its derivatives can be used as inhibitors and structure probes for human protein lysine methyltransferase SETD2.
参考文献
Yadav, M.K., et al.: BioMed Res. Int., 156987, 11 (2014); Zheng, W., et al.: J. Am. Chem. Soc., 134, 18004 (2012); Ghosh, A.K. and Liu, W.: J. Org. Chem., 61, 6175 (1996)
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