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产品编号：T535930
产品名称：(1S,2S)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine
产品CAS：167316-27-0
规格含量：2g
产品价格：面议
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产品详细介绍
标准品编号:
T535930
名称:
(1S,2S)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine
别名:
N-[(1S,2S)-2-Amino-1,2-diphenylethyl]-4-methylbenzenesulfonamide; [S-(R*,R*)]-N-(2-Amino-1,2-diphenylethyl)-4-methylbenzenesulfonamide; (1S,2S)-(+)-N-(4-Toluenesulfonyl)-1,2-diphenylethylene-1,2-diamine; (1S,2S)-(+)-N-(4-Toluenesulfonyl)-1,2-diphenylethylenediamine; (1S,2S)-(+)-N-p-Tosyl-1,2-diphenylethylenediamine; (1S,2S)-N-(4-Toluenesulfonyl)-1,2-diphenylethylenediamine; (1S,2S)-N-(p-Tolylsulfonyl)-1,2-diphenylethylenediamine; ((1S,2S)-N'-[(4-Methylphenyl)sulfonyl]-1,2-diphenyl-1,2-ethanediamine; (S,S)-N-p-Toluenesulfonyl-1,2-diphenylethylenediamine; (S,S)-TsDPEN; N-Tosyl-(1S,2S)-1,2-diphenylethylenediamine; N-[(1S,2S)-2-Amino-1,2-diphenylethyl]-4-methylbenzenesulfonamide
CAS号:
167316-27-0
分子式:
C₂₁H₂₂N₂O₂S
外观:
白色固体
熔点:
126-128°C
分子量:
366.48
储存:
冰箱
溶解度:
Chloroform, DMSO, Methanol
类别:
Building Blocks; Catalyst;
应用:
(1S,2S)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine is used as a catalyst in the synthesis of keramamine C, a carboline alkaloid that is isolated from the Okinawan sponge Amphimedon sp. (1S,2S)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine is also used as a catalyst in the synthesis of Tolvaptan (T536650), a selective oral vasopressin V2-receptor agonist that is used to treat hyponatremia.
参考文献
Hu, J., et al.: Alkaloid. New York-Acad. Press, 60, 207 (2003); Ishiyama, H., et al.: Heterocycles, 86, 1009 (2012); Schrier, R., et al.: New Engl. J. Med., 355, 2099 (2006); Yin, L., et al.: Tetrahedron-Assymetr., 21, 2390 (2010)
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